Binary Palladium–Nickel/Vulcan carbon-based nanoparticles as highly efficient catalyst for hydrogen evolution reaction at room temperature
| Autor: | Mehmet Harbi Calimli, Fatih Şen, Betül Şen, Ayşenur Aygün, Aysun Şavk, Senem Karahan Gülbay, Fulya Gulbagca |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
Characterization General Chemical Engineering Alloy chemistry.chemical_element Nanoparticle 02 engineering and technology Activation energy Borane engineering.material 010402 general chemistry 01 natural sciences Catalysis PdNi@VC chemistry.chemical_compound Dimethylamine General Chemistry 021001 nanoscience & nanotechnology 0104 chemical sciences chemistry Chemical engineering Dimethylamine Borane engineering Catalytic Reaction 0210 nano-technology Carbon Palladium |
| Zdroj: | Journal of the Taiwan Institute of Chemical Engineers. 101:92-98 |
| ISSN: | 1876-1070 |
| Popis: | Herein, Palladium-Nickel alloy nanoparticles assembled on Vulcan carbon composites (PdNi@VC) have been reported as highly efficient, stable and durable catalyst for the hydrogen evolution from dimethylamine borane. Palladium-Nickel alloy nanoparticles assembled on Vulcan carbon composites were prepared using ultrasonic reduction technique and characterized using some analytical methods. The characterization analyses revealed that Palladium-Nickel alloy nanoparticles assembled on Vulcan carbon composites have a monodisperse metal distribution and crystalline structure. Some catalytic experiments were performed, and some activation parameters such as activation energy (Ea=40.05 +/- 2 kJ/mol), activation entropy (Delta S =-132.11 +/- 1 J mol(-1) K-1) and activation enthalpy (Delta H =37.55 +/- 1 kJ mol(-1)) were calculated for catalytic reaction of dimethylamine borane. The turnover frequency (TOF) value of Palladium-Nickel alloy nanoparticles assembled on Vulcan carbon composites was found to be 283.48 h(-1), having one of the best catalytic activities among the previous heterogenous catalysts tested for dimethylamine borane (DMAB) catalytic reaction. (C) 2019 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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