Capturing polycyclic aromatic sulfur heterocycles in electron donor–acceptor complexes

Autor:	Mariia V. Samodelova, Tatyana N. Shekhovtsova, Mariia V. Ferree, Irina A. Veselova, Olga E. Eremina
Rok vydání:	2021
Předmět:	010405 organic chemistry Chemistry chemistry.chemical_element Electron donor General Chemistry Surface-enhanced Raman spectroscopy Alkylation 010402 general chemistry Photochemistry 01 natural sciences Sulfur Acceptor 0104 chemical sciences chemistry.chemical_compound Dibenzothiophene Stoichiometry
Zdroj:	Mendeleev Communications. 31:326-329
ISSN:	0959-9436
DOI:	10.1016/j.mencom.2021.04.015
Popis:	Stoichiometry and stability of electron donor–acceptor complexes formed by dibenzothiophene and its alkylated derivatives with DDQ and TCNE in nonpolar organic solvents has been investigated. 4,6-Dimethyldibenzothiophene produces the most stable 1: 1 complex with DDQ in agreement with energy levels of the π-donors HOMOs and π-acceptors LUMOs calculated by DFT. The results make possible an employment of the complexes for multiplex determination of polycyclic aromatic pollutants using surface enhanced Raman spectroscopy.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b59dfb668ca56cf8df2ee44dcecd0d8f https://doi.org/10.1016/j.mencom.2021.04.015 Zobrazit plný text záznamu Full Text from ScienceDirect