A convenient conversion of terminal alkenes into homologous unsaturated and doubly unsaturated esters

Autor:	Samir Z. Zard, Bill C. Hawkins, Nina Tölle, Victoria L. Paddock
Přispěvatelé:	Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)
Rok vydání:	2012
Předmět:	chemistry.chemical_compound chemistry 010405 organic chemistry [CHIM.ORGA]Chemical Sciences/Organic chemistry Organic Chemistry Organic chemistry Sulfoxide Xanthate Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences
Zdroj:	Organic Letters Organic Letters, American Chemical Society, 2012, 14 (4), pp.1020-1023. ⟨10.1021/ol203387r⟩
ISSN:	1523-7052 1523-7060
Popis:	International audience; Unsaturated and doubly unsaturated esters have been synthesized in two steps by the application of a radical xanthate transfer process of a simple methylsulfoxide starting material to a range of terminal alkenes. syn-Elimination of the sulfoxide gives α,β-unsaturated esters, which coupled with a xanthate elimination yields α,β,γ,δ-unsaturated esters. © 2012 American Chemical Society.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b59b33daf711d91a185bb76394846352 https://pubmed.ncbi.nlm.nih.gov/22296044 Zobrazit plný text záznamu