High-pressure XRD study of β-Na0.33V2O5
Autor: | Siegfried Horn, S. Frank, Christine A. Kuntscher, G. Obermeier, Michael Hanfland, Alexej Pashkin, K. Rabia |
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Rok vydání: | 2009 |
Předmět: |
Diffraction
Materials science Crystal structure Pressure dependence Condensed Matter Physics Metal Condensed Matter::Materials Science Crystallography visual_art High pressure Lattice (order) Compressibility visual_art.visual_art_medium Condensed Matter::Strongly Correlated Electrons Monoclinic crystal system |
Zdroj: | High Pressure Research. 29:504-508 |
ISSN: | 1477-2299 0895-7959 |
DOI: | 10.1080/08957950903422436 |
Popis: | We have investigated the pressure-dependent structural properties of the quasi-one-dimensional metal at room temperature by high-resolution angle-dispersive powder X-ray diffraction. According to our structural data, the crystal lattice of β-Na0.33V2O5 remains monoclinic (space group C2/m) up to 20 GPa. The smallest compressibility is found along the conducting b-axis. We observe an anomaly in the pressure dependence of the lattice parameters and the volume of the unit cell in the range 12–15 GPa, in agreement with the pressure-dependent optical properties. |
Databáze: | OpenAIRE |
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