Light-induced spin crossover—Solution and solid-state processes
| Autor: | Maciej Lorenc, Roman Bertoni, Cédric Desplanches, Guillaume Chastanet |
|---|---|
| Přispěvatelé: | Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB), Université de Bordeaux (UB)-Institut Polytechnique de Bordeaux-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), Institut de Physique de Rennes (IPR), Université de Rennes 1 (UR1), Université de Rennes (UNIV-RENNES)-Université de Rennes (UNIV-RENNES)-Centre National de la Recherche Scientifique (CNRS), the Aquitaine Region, the CNRS, the University of Bordeaux, and the ANR for their support. The Région Bretagne, Rennes Metropole, CNRS, Univérsité de Rennes 1, and ANR for a sustained support. The authors thank the French network 'magnétisme et commutation moléculaires' for the exchanges and the collaborative framework it affords., Université de Rennes (UR)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
[PHYS]Physics [physics]
Materials science General Chemical Engineering Solid-state Relaxation studies 02 engineering and technology General Chemistry Trapping Spin crossover (SCO) [CHIM.MATE]Chemical Sciences/Material chemistry Photothermal therapy Optical spectra 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Ion Spin crossover Chemical physics Excited state Light induced LIESST Absorption (chemistry) 0210 nano-technology Ultrafast spectroscopy |
| Zdroj: | Comptes Rendus. Chimie Comptes Rendus. Chimie, Académie des sciences (Paris), 2018, 21 (12), pp.1075-1094. ⟨10.1016/j.crci.2018.02.011⟩ Comptes Rendus. Chimie, 2018, 21 (12), pp.1075-1094. ⟨10.1016/j.crci.2018.02.011⟩ |
| ISSN: | 1631-0748 1878-1543 |
| Popis: | International audience; This article overviews the different light-induced spin-crossover processes that are induced using ligand photoreaction, photothermal effects, or optical absorption of the center metallic ion. A particular attention is drawn on the light-induced excited spin-state trapping effect, the most studied phenomenon, by discussing the recent developments in terms of description of the initial photoswitching process and the mechanisms developing at different time scales, as well as the lifetime of the photoinduced state. |
| Databáze: | OpenAIRE |
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