Chemiluminescence detection of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and related nitramine explosives
| Autor: | Neil W. Barnett, Duncan Graham, David N. Donaldson, Kieran F. Lim, Chad Prior, Kent M. Agg, Claire E. Lenehan, Paul S. Francis |
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| Rok vydání: | 2012 |
| Předmět: |
Analyte
Explosive material Screening test Inorganic chemistry Analytical chemistry chemistry.chemical_element Analytical Chemistry law.invention Bipyridine chemistry.chemical_compound 2 2'-Dipyridyl Explosive Agents law Organometallic Compounds Nitrobenzenes Chemiluminescence Flow injection analysis Aniline Compounds Triazines Chemistry Ruthenium Zinc Reagent Flow Injection Analysis Luminescent Measurements Mercuric Chloride |
| Zdroj: | Talanta. 88:743-748 |
| ISSN: | 0039-9140 |
| Popis: | A simple controlled chemical reduction of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and related nitramine compounds with zinc amalgam generates species that elicit intense chemiluminescence with tris(2,2'-bipyridine)ruthenium(III), which extends this widely utilised chemiluminescence reagent to a new class of analyte and presents a sound chemical basis for a screening test for nitramine high explosives. Examination of the chemiluminescence profiles under stopped-flow conditions revealed contributions from multiple transient species formed in the initial reduction step. |
| Databáze: | OpenAIRE |
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