Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand
| Autor: | Mastropierro, Pasquale, Kennedy, Alan R., Hevia, Eva |
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| Rok vydání: | 2022 |
| Předmět: |
Models
Molecular Metals and Alloys General Chemistry 000 Computer science knowledge & systems Ligands Amides Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials QD450 540 Chemie 540 Chemistry Potassium Materials Chemistry Ceramics and Composites 570 Life sciences biology 000 Informatik Wissen Systeme 570 Biowissenschaften Biologie |
| Zdroj: | Mastropierro, Pasquale; Kennedy, Alan R.; Hevia, Eva (2022). Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand. Chemical Communications, 58(34), pp. 5292-5295. Royal Society of Chemistry 10.1039/D2CC00979J |
| ISSN: | 1364-548X 1359-7345 |
| Popis: | Combining a bulky bis(amide) and a reactive one-coordinate TMP (2,2,6,6-tetramethylpiperidide) ligand, a new mixed K/Zn heteroleptic base has been developed for regioselective zincation of fluoroarenes. This special ligand set allows for trapping and structural authentication of the first intermediates of direct Zn-H exchange of fluoroarenes obtained via deprotonative metallation, providing mechanistic insights of the processes involved. |
| Databáze: | OpenAIRE |
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