The Effect of Metal Salts on The Structures of 2,2-Dimethylglutarate Complexes with a Flexible 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
| Autor: | Okan Zafer Yeşilel, Pelin Köse Yaman, Mürsel Arıcı, Hakan Erer |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Diffraction
chemistry.chemical_classification 010405 organic chemistry Chemistry Metal salts Organic Chemistry Infrared spectroscopy Polymer 010402 general chemistry 01 natural sciences Hydrothermal circulation 0104 chemical sciences Analytical Chemistry Inorganic Chemistry Crystallography Luminescence Single crystal Spectroscopy Powder diffraction |
| Popis: | Five new coordination polymers, {[Co2(mu-dmg)(2)(mu-p-tmbix)(2)]center dot H2O}(n) (1), [ CO2(mu-dmg)(2)(mu-p-tmbix)(2)](n) (2), [Zn-2(mu-dmg)(2)(mu-P-tmbix)(2)](n) (3), [Cd(mu-dmg)(mu-p-tmbix)](n) (4) and [Cd(mu-dmg)(mu-p-tmbix)]center dot H2O}(n) (5) were successfully synthesized by using H(2)dmg and p-tmbix ligands under hydrothermal conditions (p-tmbix = 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene and H(2)dmg = 2,2-dimethylglutaric acid). Their structures were characterized by single crystal X-ray diffraction, elemental analyses, IR spectroscopy and powder X-ray diffraction (PXRD). Single crystal X-ray diffraction analysis revealed that compounds 1-4 displayed 3D frameworks and 2D network, respectively, while compound 5 exhibited two-fold interpenetrated 3D structure with 6(6)-dia topology. Furthermore, luminescence properties and thermal analyses (TG, DTA and DTA) of the compounds were investigated. (C) 2020 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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