Ruthenium complexes of sterically-hindered pentaarylcyclopentadienyl ligands

Autor:	Ryosuke Asato, Yohan Gisbert, Tsuyoshi Kawai, Gwénaël Rapenne, Claire Kammerer, Colin J. Martin, Seifallah Abid
Přispěvatelé:	Nara Institute of Science and Technology,Division of Materials Science (NAIST), International Collaborative Laboratory for Supraphotoactive Systems, Centre d'élaboration de matériaux et d'études structurales (CEMES), Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut National des Sciences Appliquées (INSA)-Université de Toulouse (UT)-Institut de Chimie de Toulouse (ICT), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Institut National des Sciences Appliquées - Toulouse (INSA Toulouse), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Nara Institute of Science and Technology, Groupe NanoSciences (CEMES-GNS), Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS), MEXT Program for Promoting the Enhancement of Research Universities in NAIST- JSPS KAKENHI grant in aid for Scientific Research on Innovative Areas 'Molecular Engine (No. 8006)' 18H05419. - JSPS KAKENHI Grant-in-Aid for Early-Career Scientists (19K15312)- JSPS KAKENHI Grant-in-Aid for Challenging Research (20K21131)., European Project: 766864,MEMO
Jazyk:	angličtina
Rok vydání:	2021
Předmět:	Steric effects Chemistry Ligand General Chemical Engineering polycyclic compounds chemistry.chemical_element [CHIM]Chemical Sciences General Chemistry Combinatorial chemistry Ruthenium
Zdroj:	RSC Advances RSC Advances, 2021, 11 (33), pp.20207-20215. ⟨10.1039/d1ra03875c⟩
ISSN:	2046-2069
Popis:	International audience; The synthesis of ruthenium complexes incorporating an overcrowded pentaarylcyclopentadienyl ligand has been investigated, and higher efficiency has been reached using chlorine-functionalised precursors when compared with their brominated counterparts. A new methodology for the preparation of chlorocyclopentadienes has been developed which is well adapted for highly sterically hindered compounds and works with either electron rich or poor systems.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b4f375097a3a12e657a9aed3c333488f https://hal.science/hal-03636821 Zobrazit plný text záznamu