Adsorption of chlorinated hydrocarbons from aqueous solutions by wetted and non-wetted synthetic sorbents: dynamics
Autor: | Rexwinkel, G., Rexwinkel, Glenn, Berkhout, J.T.A.M., Heesink, Albertus B.M. |
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Přispěvatelé: | Faculty of Science and Technology |
Rok vydání: | 2003 |
Předmět: |
Mass transfer coefficient
Sorbent Chromatography Aqueous solution Chemistry Non-wetted and mass transfer coefficients Applied Mathematics General Chemical Engineering General Chemistry Sherwood number Modelling Industrial and Manufacturing Engineering Solvent IR-74952 Kinetics Adsorption Chemical engineering Mass transfer METIS-217433 Wetting |
Zdroj: | Chemical engineering science, 58(7), 1301-1304. Elsevier |
ISSN: | 0009-2509 |
DOI: | 10.1016/s0009-2509(02)00428-1 |
Popis: | In the present investigation the dynamics of the adsorption of several chlorinated hydrocarbons onto wetted and non-wetted synthetic sorbents was studied. A single particle model was developed to describe the adsorption behavior. The values of the mass transfer coefficient, needed to describe the experimental results, were found to be considerably less than those predicted from theory. The difference between measured and expected mass transfer coefficient was found to increase with non-ideality of the solute and to depend on type of sorbent. Apparently, the rate of mass transfer does not only depend on hydrodynamics but also on possible interaction between solute, solvent and sorbent. |
Databáze: | OpenAIRE |
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