Comparison of Mechanochemical Chain Scission Rates for Linear versus Three-Arm Star Polymers in Strong Acoustic Fields
| Autor: | Andrew J. Boydston, Gregory I. Peterson, Derek C. Church |
|---|---|
| Rok vydání: | 2022 |
| Předmět: |
chemistry.chemical_classification
endocrine system Acoustic field Materials science Polymers and Plastics Chain scission Organic Chemistry Linear system Polymer Star (graph theory) Inorganic Chemistry Reaction rate constant chemistry Star polymer Chemical physics Polymer chemistry Materials Chemistry Bond cleavage |
| Zdroj: | ACS macro letters. 3(7) |
| ISSN: | 2161-1653 |
| Popis: | The effect of star versus linear polymer architecture on the rates of mechanochemically induced bond scission has been explored. We determined rate constants for chain scission of parent linear and star polymers, from which daughter fragments were cleanly resolved. These studies confirm a mechanistic interpretation of star polymer chain scission that is governed by the spanning rather than total molecular weight. We further demonstrate the preserved rate of site-selective mechanophore activation across two different polymer structures. Specifically, we observed consistent activation rate constants from three-arm star and linear polymer analogues, despite the Mn of the star polymer being 1.5 times greater than that of the linear system. |
| Databáze: | OpenAIRE |
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