The coupling of supercritical fluid chromatography and field ionization time-of-flight high-resolution mass spectrometry for rapid and quantitative analysis of petroleum middle distillates
| Autor: | Gary J. Dechert, John W. Diehl, Frank P. Disanzo, Kuangnan Qian |
|---|---|
| Rok vydání: | 2004 |
| Předmět: |
chemistry.chemical_classification
Chromatography business.industry Elution 010401 analytical chemistry Analytical chemistry General Medicine 010402 general chemistry Mass spectrometry 01 natural sciences Atomic and Molecular Physics and Optics 0104 chemical sciences law.invention Mass Hydrocarbon Petroleum product chemistry law Field desorption Supercritical fluid chromatography Flame ionization detector business Spectroscopy |
| Zdroj: | European journal of mass spectrometry (Chichester, England). 10(2) |
| ISSN: | 1469-0667 |
| Popis: | We report the first coupling of supercritical fluid chromatography (SFC) with field ionization time-of-flight high-resolution mass spectrometry (FI-ToF HRMS), in parallel with ultraviolet (UV) detection and flame ionization detection (FID), for rapid and quantitative analysis of petroleum middle distillates. SFC separates petroleum middle distillates into saturates and 1- to 3-ring aromatics. FI generates molecular ions for hydrocarbon species eluted from the SFC. The high resolution and exact mass measurements by ToF mass spectrometry provide elemental compositions of the molecules in the petroleum product. The amounts of saturates and aromatic ring types were quantified using the parallel SFC-FID assisted by SFC-UV. With a proper carbon–number calibration, the detailed composition of the petroleum middle distillate was rapidly determined. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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