Asymmetric autocatalysis initiated by achiral nucleic acid base adenine: implications on the origin of homochirality of biomolecules
| Autor: | Taichi Hanasaki, Hiroko Mineki, Kenso Soai, Tsuneomi Kawasaki, Arimasa Matsumoto |
|---|---|
| Rok vydání: | 2012 |
| Předmět: |
chemistry.chemical_classification
Adeninium dinitrate Base (chemistry) Stereochemistry Biomolecule Adenine Circular Dichroism Metals and Alloys Molecular Conformation Stereoisomerism General Chemistry Crystallography X-Ray Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Autocatalysis chemistry Materials Chemistry Ceramics and Composites Nucleic acid Homochirality Chirality (chemistry) |
| Zdroj: | Chemical communications (Cambridge, England). 48(85) |
| ISSN: | 1364-548X |
| Popis: | Enantiomorphous crystals of adeninium dinitrate acted as the source of chirality in asymmetric autocatalysis producing highly enantioenriched (S)- and (R)-5-pyrimidyl alkanols, with the absolute configurations corresponding to that of crystals. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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