New acylnitroso compounds for the asymmetric oxyamination of dienes

Autor: C. Mineur, Léon Ghosez, Georges Dive, S. J. Mccarthy, Veronique Gouverneur, D. Belotti
Rok vydání: 1998
Předmět:
Zdroj: Tetrahedron. 54:10537-10554
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(98)00504-3
Popis: A series of new enantiomerically pure acylnitroso compounds have been prepared and tested as dienophiles for the asymmetric oxyamination of dienes. Very high selectivities were obtained with acylnitroso compounds derived from diphenylmethoxymethyl pyrrolidine 2c, the C-2-symmetric pyrrolidines 2d-e and camphorsultam 2f. (C) 1998 Elsevier Science Ltd. All rights reserved.
Databáze: OpenAIRE