Commensurate freezing of n-Alkanes in silicalite

Autor:	van Jhc Jan Hooff, van Wjm Willy Well, van Ra Rutger Santen, JP Jillus Wolthuizen, Berend Smit
Přispěvatelé:	HIMS (FNWI), Inorganic Materials & Catalysis
Jazyk:	angličtina
Rok vydání:	1995
Předmět:	N alkanes Chemistry Desorption Inorganic chemistry Thermochemistry Physical chemistry Single step General Medicine General Chemistry Catalysis
Zdroj:	Angewandte Chemie. International edition in English, 34, 2543-.... John Wiley and Sons Ltd Angewandte Chemie-International Edition, 34(22), 2543-2544. Wiley
ISSN:	1521-3773 1433-7851 0570-0833
Popis:	Very surprising desorption behavior from silicalite is shown by n-hexane and n-heptane among the n-alkanes ranging from n-butane to n-decane. While n-hexane and n-heptane show a two-step desorption, longer and shorter n-alkanes desorb in a single step. These results can be explained by commensurate freezing, a phenomenon which was predicted very recently by computer simulations.
Databáze:	OpenAIRE
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