Simple route to new oxadiazaboroles and oxadiazoles via amidoximes

Autor: Zoltán Mucsi, Péter Nemes, Mihály V. Pilipecz, Pál Szabó, Ruth Deme, Tamás R. Varga, Péter Králl, Zoltán Vincze
Rok vydání: 2020
Předmět:
DOI: 10.6084/m9.figshare.12195717
Popis: The novel push–pull alkene, the 2-(nitro-nitrosomethylene)-pyrrolidine with numerous aliphatic or aromatic amines as nucleophiles afforded amidoximes. Various substituted oxadiazaborole and oxadiazole derivatives were prepared starting from these amidoximes, widening the synthetic applicability of the push–pull alkenes. Acylation of the amidoximes was also examined. The mechanism of the amidoxime formation was investigated by computational methods.
Databáze: OpenAIRE