The Photochemistry of 4,5-Carbomethoxy-1,2,3-thiadiazole: Direct Observation of Thiirene Formation and Its Decay in Solution
| Autor: | Hoi Ling Luk, Yunlong Zhang, Gotard Burdzinski, Carolyn S. Reid, Matthew S. Platz, Christopher M. Hadad |
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| Rok vydání: | 2013 |
| Předmět: |
Acetonitriles
Light Molecular Structure Spectrophotometry Infrared biology Chemistry Direct observation Thiophenes Photochemical Processes Photochemistry biology.organism_classification Thiirene Solutions chemistry.chemical_compound Thiadiazoles Ultrafast laser spectroscopy Thiophene Tetra Molecule Spectrophotometry Ultraviolet Physical and Theoretical Chemistry Acetonitrile Dimerization |
| Zdroj: | The Journal of Physical Chemistry A. 117:4551-4555 |
| ISSN: | 1520-5215 1089-5639 |
| DOI: | 10.1021/jp4003406 |
| Popis: | The photochemistry of 4,5-carbomethoxy-1,2,3-thiadiazole in solution was studied at room temperature with use of UV-vis and IR transient absorption spectroscopies (λ(ex) = 266 nm). Ultrafast time-resolved techniques demonstrate that there is a very fast rise ( |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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