TiO2 nanorod-based photoelectrodes for dye solar cells with tunable morphological features
Autor: | M. Manca [1], L. De Marco [1], R. Giannuzzi[1], R. Agosta [1], C. Dwivedi [4], A. Qualtieri [1], P. D. Cozzoli [2, V. Dutta [4], G. Gigli [1, 2 |
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Přispěvatelé: | Manca, M., De Marco, L., Giannuzzi, R., Agosta, R., Dwivedi, C., Qualtieri, A., Dutta, V., Cozzoli, Pantaleo Davide, Gigli, Giuseppe |
Jazyk: | angličtina |
Rok vydání: | 2014 |
Předmět: |
Materials science
Metals and Alloys Nanoparticle Nanotechnology 02 engineering and technology Surfaces and Interfaces 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences TiO2 nanorods Photoelectrodes Electrochemical impedance spectroscopy Nanocrystalline material 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention Nanocrystal law Solar cell Materials Chemistry Nanorod 0210 nano-technology Mesoporous material |
Zdroj: | Thin solid films 568 (2014): 122–130. doi:10.1016/j.tsf.2013.10.155 info:cnr-pdr/source/autori:M. Manca [1], L. De Marco [1], R. Giannuzzi[1], R. Agosta [1], C. Dwivedi [4], A. Qualtieri [1], P. D. Cozzoli [2,3], V. Dutta [4], G. Gigli [1,2,3]/titolo:TiO2 nanorods-based photoelectrodes for dye solar cells with tunable morphological features/doi:10.1016%2Fj.tsf.2013.10.155/rivista:Thin solid films (Print)/anno:2014/pagina_da:122/pagina_a:130/intervallo_pagine:122–130/volume:568 Thin Solid Films |
DOI: | 10.1016/j.tsf.2013.10.155 |
Popis: | The ability to create photoanodes in which the structural and morphological features of the underlying TiO2 nanocrystalline constituents provide a tailored nanotexture with a higher degree of functionality still represents an indispensible step toward boosting the ultimate light-to electricity conversion of photoelectrochemical devices. This is especially evident for dye solar cells. In this paper we have systematically analyzed the impact of several different TiO2 nanorod morphologies on the most meaningful electrochemical features of the mesoporous photoelectrode of a dye solar cell. The most relevant findings have been then adopted as design criteria to realize an optimized multilayered photoelectrode with a properly engineered architecture which embodies three different breeds of nanocrystal with synergistic peculiarities. It exhibited superior power conversion efficiencies with respect to conventional nanoparticle-based reference film. |
Databáze: | OpenAIRE |
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