Introducing Dimensionality to the Archetypical Mn12 Single-Molecule Magnet: a Family of [Mn12]n Chains
| Autor: | Corrales, S. A., Cain, J. M., Uhlig, K. A., Mowson, A. M., Papatriantafyllopoulou, Constantina, Peprah, M. K., Ozarowski, A., Tasiopoulos, Anastasios J., Christou, George, Meisel, M. W., Lampropoulos, Christos |
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| Přispěvatelé: | Tasiopoulos, Anastasios J. [0000-0002-4804-3822], Papatriantafyllopoulou, Constantina [0000-0002-5652-7747], Lampropoulos, Christos [0000-0001-9065-1453] |
| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Magnetism Ligand Chemistry 010402 general chemistry 01 natural sciences Spectral line 0104 chemical sciences law.invention Inorganic Chemistry Crystallography Chain (algebraic topology) law Magnet Single-molecule magnet Physical and Theoretical Chemistry Electron paramagnetic resonance Curse of dimensionality |
| Zdroj: | Inorganic chemistry Inorg.Chem. |
| ISSN: | 1520-510X 0020-1669 |
| DOI: | 10.1021/acs.inorgchem.6b00058 |
| Popis: | The [Mn12O12(O2CR)16(L4)] family (R = various L = terminal ligand) of clusters holds a special place in molecular magnetism they are the most well-studied single-molecule magnets (SMMs). Targeted linkage of these SMMs has now been achieved for the first time. The resulting chain structures have been confirmed crystallographically, and the magnetic properties, up to 1.14 GPa, and high-field electron paramagnetic resonance spectra have been collected and analyzed. © 2016 American Chemical Society. 55 4 1367 1369 Cited By :3 |
| Databáze: | OpenAIRE |
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