Synthesis and Characterization of Novel Triarylmethane-Based Dyes for Thermally Stable Blue Color Filters

Autor: Jong Mok Park, Do-Hoon Hwang, Chan Gyu Lee, Hoyoul Kong, Seo-Hyun Jung, Gyu Sung Lee, Young Ii Park, Jeong Yong Park
Rok vydání: 2019
Předmět:
Zdroj: Journal of Nanoscience and Nanotechnology. 19:4782-4786
ISSN: 1533-4880
DOI: 10.1166/jnn.2019.16682
Popis: Two new triarylmethane-based dye molecules with a dimeric structure, TAM-1 and TAM-2, were designed and synthesized as potential blue color filter materials for liquid-crystal displays. The dimeric structure of TAM-1 was designed to improve the thermal stability of a well-known blue dye, Victoria Blue BO. TAM-2 was designed to further improve the solubility of TAM-1 by introducing long alkyl ester groups. The synthesized dyes TAM-1 and TAM-2 were transmissive in the wavelength range of 410-460 nm and showed good thermal stability with 5% weight degradation temperatures (T5d) of 259 °C and 289 °C, respectively, and less than 1% of weight loss at 230 °C. Moreover, TAM-2 showed excellent solubility (20.1 wt%) as opposed to Victoria Blue BO (0.03 wt%) and TAM-1 (3.5 wt%) in PGMEA.
Databáze: OpenAIRE