Chiroptical Sensing: A Conceptual Introduction
Autor: | Nataša Poklar Ulrih, Raquel Pereira-Cameselle, José Lorenzo Alonso-Gómez, Ani Ozcelik, Ana G. Petrovic |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: |
010405 organic chemistry
Computer science 2306.04 Química de Los Compuestos Bicíclicos chiral design Review 010402 general chemistry lcsh:Chemical technology 01 natural sciences Biochemistry Atomic and Molecular Physics and Optics 0104 chemical sciences Analytical Chemistry chiroptical systems 2306.16 Esteroquímica y Análisis Conformacional lcsh:TP1-1185 Biochemical engineering Sensitivity (control systems) sensing applications Electrical and Electronic Engineering Instrumentation 1203.25 Diseño de Sistemas Sensores theoretical simulations |
Zdroj: | Sensors, Vol 20, Iss 4, p 974 (2020) Investigo. Repositorio Institucional de la Universidade de Vigo Universidade de Vigo (UVigo) Sensors (Basel, Switzerland) |
ISSN: | 1424-8220 |
Popis: | Chiroptical responses have been an essential tool over the last decades for chemical structural elucidation due to their exceptional sensitivity to geometry and intermolecular interactions. In recent times, there has been an increasing interest in the search for more efficient sensing by the rational design of tailored chiroptical systems. In this review article, advances made in chiroptical systems towards their implementation in sensing applications are summarized. Strategies to generate chiroptical responses are illustrated. Theoretical approaches to assist in the design of these systems are discussed. The development of efficient chiroptical reporters in different states of matter, essential for the implementation in sensing devises, is reviewed. In the last part, remarkable examples of chiroptical sensing applications are highlighted. Xunta de Galicia | Ref. ED431F 2016/005, GRC2019/24 Interreg | Ref. 0245_IBEROS_1_E Slovenian Research Agency | Ref. P4-0121 |
Databáze: | OpenAIRE |
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