Fullerene Complexation in a Hydrogen-Bonded Porphyrin Receptor via Induced-Fit: Cooperative Action of Tautomerization and C-H···π Interactions

Autor: Augustina Jozeliu̅naitė, Algirdas Neniškis, Arnau Bertran, Alice M. Bowen, Marilena Di Valentin, Steponas Raišys, Paulius Baronas, Karolis Kazlauskas, Linas Vilčiauskas, Edvinas Orentas
Rok vydání: 2022
Předmět:
Zdroj: Journal of the American Chemical Society.
ISSN: 1520-5126
Popis: A supramolecular chiral hydrogen-bonded tetrameric aggregate possessing a large cavity and tetraarylporphyrin substituents was assembled using alternating 4H- and 2H-bonds between ureidopyrimidinone and isocytosine units, respectively. The aggregation mode was rationally shifted from social to narcissistic self-sorting by changing urea substituent size only. The H-bonded tetramer forms a strong complex with C
Databáze: OpenAIRE