Copper catalysis with redox-active ligands
| Autor: | Marine Desage-El Murr, Cheriehan Hessin, Yufeng Ren, Agnideep Das |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2020 |
| Předmět: |
Coordination sphere
Electronic participation Organic Chemistry chemistry.chemical_element Review bioinspired catalysis redox-active ligands Combinatorial chemistry Copper Catalysis lcsh:QD241-441 Electron transfer Chemistry chemistry lcsh:Organic chemistry biomimetic copper complexes Redox active Reactivity (chemistry) lcsh:Q cooperative catalysis lcsh:Science redox catalysis |
| Zdroj: | Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry, Vol 16, Iss 1, Pp 858-870 (2020) |
| ISSN: | 1860-5397 |
| Popis: | Copper catalysis finds applications in various synthetic fields by utilizing the ability of copper to sustain mono- and bielectronic elementary steps. Further to the development of well-defined copper complexes with classical ligands such as phosphines and N-heterocyclic carbenes, a new and fast-expanding area of research is exploring the possibility of a complementing metal-centered reactivity with electronic participation by the coordination sphere. To achieve this electronic flexibility, redox-active ligands can be used to engage in a fruitful “electronic dialogue” with the metal center, and provide additional venues for electron transfer. This review aims to present the latest results in the area of copper-based cooperative catalysis with redox-active ligands. |
| Databáze: | OpenAIRE |
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