Quinone-catalyzed oxidative deformylation: synthesis of imines from amino alcohols
| Autor: | Johnny H. Phan, Shrikant S. Londhe, Xinyun Liu, Michael D. Clift, Benjamin John Haugeberg |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Letter
Imine deformylation Oxidative phosphorylation 010402 general chemistry 01 natural sciences Catalysis lcsh:QD241-441 chemistry.chemical_compound lcsh:Organic chemistry organocatalysis lcsh:Science Bond cleavage Primary (chemistry) catalysis 010405 organic chemistry Organic Chemistry organic synthesis Combinatorial chemistry 0104 chemical sciences 3. Good health Quinone Chemistry chemistry Organocatalysis lcsh:Q Organic synthesis |
| Zdroj: | Beilstein Journal of Organic Chemistry, Vol 13, Iss 1, Pp 2895-2901 (2017) Beilstein Journal of Organic Chemistry |
| ISSN: | 1860-5397 |
| Popis: | A new method for imine synthesis by way of quinone-catalyzed oxidative deformylation of 1,2-amino alcohols is reported. A wide range of readily accessible amino alcohols and primary amines can be reacted to provide N-protected imine products. The methodology presented provides a novel organocatalytic approach for imine synthesis and demonstrates the synthetic versatility of quinone-catalyzed oxidative C–C bond cleavage. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|