Self-forming double-crosslinked hydrogels by the marriage of catechols and enzyme mimetic polymers
| Autor: | Yaqing Chen, Erik Misselwitz, Asger Holm Agergaard, Amanda Andersen, Carsten Pedersen, Henrik Birkedal |
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| Rok vydání: | 2022 |
| Předmět: |
Polymers
Catechols PROTEIN macromolecular substances complex mixtures Catalysis ZINC Metals/chemistry Polymers/chemistry Materials Chemistry MIMICKING Cross-Linking Reagents/chemistry organic chemicals technology industry and agriculture Metals and Alloys Hydrogels MUSSEL General Chemistry Hydrogels/chemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials TYROSINASE Cross-Linking Reagents Metals LINKING MECHANICS Ceramics and Composites COMPLEXES COPPER(II) Catechols/chemistry Oxidation-Reduction NEREIS |
| Zdroj: | Chen, Y, Misselwitz, E, Agergaard, A H, Andersen, A, Pedersen, C & Birkedal, H 2022, ' Self-forming double-crosslinked hydrogels by the marriage of catechols and enzyme mimetic polymers ', Chemical communications (Cambridge, England), vol. 58, no. 45, pp. 6526-6529 . https://doi.org/10.1039/d2cc01290a |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/d2cc01290a |
| Popis: | Self-forming double-crosslinked (DC) hydrogels were designed by incorporating enzyme-mimicking metal coordination polymer crosslinks and catechol chemistry. A macromolecular tris-histidine copper complex acted both as part of the hydrogel network and as a catalyst of catechol oxidation to induce a second hydrogel network by covalent crosslinking of catechol functionalized polymers thus giving catalytic control over hydrogel crosslinking. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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