Alkylation of Isobutane/2-Butene Over Modified FAU-Type Zeolites
| Autor: | Min Yeoung Gim, Eo Jin Lee, In Kyu Song, Jong Won Lee, Youngsoo Ro |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
inorganic chemicals
Materials science Biomedical Engineering chemistry.chemical_element Bioengineering 02 engineering and technology General Chemistry Alkylation 010402 general chemistry 021001 nanoscience & nanotechnology Condensed Matter Physics 01 natural sciences 2-Butene Hydrothermal circulation 0104 chemical sciences Catalysis chemistry.chemical_compound chemistry Isobutane General Materials Science 0210 nano-technology Mesoporous material Selectivity Carbon Nuclear chemistry |
| Zdroj: | Journal of Nanoscience and Nanotechnology. 18:6547-6551 |
| ISSN: | 1533-4880 |
| DOI: | 10.1166/jnn.2018.15665 |
| Popis: | A serious of mesoporous La-zeolite X catalysts (La-x-Zeol X (x = 0, 0.25, 0.5, 0.75, 1.0, and 2.0)) were prepared by a hydrothermal method with a variation of carbon template content (x, wt%). The prepared catalysts were applied to the isobutane/2-butene alkylation. Mesopore volume of the catalysts increased with increasing carbon template content, while acidity of the catalysts decreased with increasing carbon template content. In the catalytic reaction, productivity of C8 alkylate (C8 alkylate g/g-catalyst) and selectivity for C8 alkylate showed volcano-shaped trends with respect to carbon template content. Among the catalysts, La-0.5-Zeol X showed the highest productivity and selectivity for C8 alkylate. The maximum productivity and selectivity for C8 alkylate over La-0.5-Zeol X were due to the offset of two opposite trends between mesopore volume and acidity of La-x-Zeol X catalysts. |
| Databáze: | OpenAIRE |
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