Origin of Enantioselectivity in the Jacobsen Epoxidation of Olefins

Autor:	László Kürti, E. J. Corey, Megan M. Blewett
Rok vydání:	2009
Předmět:	Steric effects Chemistry Jacobsen epoxidation Organic Chemistry Stereoisomerism Alkenes Photochemistry Biochemistry Substrate Specificity Epoxy Compounds Substrate specificity Organic chemistry Physical and Theoretical Chemistry Selectivity
Zdroj:	Organic Letters. 11:4592-4595
ISSN:	1523-7052 1523-7060
DOI:	10.1021/ol901859d
Popis:	It is proposed that facial selectivity in the Jacobsen epoxidation is determined by electrostatic and steric factors with a two-step pathway involving a carbocationic intermediate.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b274fbc30cc8ba25b4021619163cc48f https://doi.org/10.1021/ol901859d Zobrazit plný text záznamu