A formulator’s cut of the phase prism for optimizing selective metal extraction
Autor: | Sandrine Dourdain, Thomas Zemb, Werner Kunz, Tobias Lopian |
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Přispěvatelé: | Institute of Physical and Theoretical Chemistry, Universität Regensburg, Tri ionique par les Systèmes Moléculaires auto-assemblés (LTSM), Institut de Chimie Séparative de Marcoule (ICSM - UMR 5257), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Montpellier (UM)-Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA) |
Rok vydání: | 2018 |
Předmět: |
Materials science
business.industry Extraction (chemistry) Waste material 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Curvature 01 natural sciences Stripping (fiber) 0104 chemical sciences Metal Colloid and Surface Chemistry Phase (matter) visual_art visual_art.visual_art_medium [CHIM]Chemical Sciences Prism 0210 nano-technology Process engineering business ComputingMilieux_MISCELLANEOUS Phase diagram |
Zdroj: | Colloids and Surfaces A: Physicochemical and Engineering Aspects Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 557, pp.2-8. ⟨10.1016/j.colsurfa.2018.08.022⟩ Colloids and Surfaces A: Physicochemical and Engineering Aspects, Elsevier, 2018, 557, pp.2-8. ⟨10.1016/j.colsurfa.2018.08.022⟩ |
ISSN: | 0927-7757 |
Popis: | Solvent-based liquid-liquid extraction and stripping is the key separation method at the basis of all hydrometallurgical processes, such as those used to retrieve strategic metals from ores or waste material. During formulation of an efficient extraction system, chemical engineers often encounter instabilities and the formation of undesired phases. In order to avoid the appearance of those in practice, we propose a simple and convenient approach of the phase diagram, based on mole ratio of cations as the variable that controls interfacial curvature. The proposed formulator’s cut through the Gibbs phase prism is more adapted than fish-cuts or similar ones in the case of extraction and stripping formulation optimized against variation in the feed composition. |
Databáze: | OpenAIRE |
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