Sensing ultrashort electronic coherent beating at conical intersections by single-electron pulses

Autor:	Shahaf Asban, Daniel Keefer, Vladimir Y. Chernyak, Shaul Mukamel
Rok vydání:	2022
Předmět:	Multidisciplinary
Zdroj:	Proceedings of the National Academy of Sciences. 119
ISSN:	1091-6490 0027-8424
DOI:	10.1073/pnas.2205510119
Popis:	Significance In a theoretical study, we present an ultrafast technique for probing time-dependent molecular charge densities. An ultrafast optical pump first brings the molecule into an electronic nonstationary state. This is followed by coherent inelastic scattering of a broadband single-electron probe pulse with a variable delay T , which is detected spectrally. The technique is applied to reveal phase-sensitive background-free coherent electron beating in the conical intersection passage in uracil and reveals the otherwise elusive coherent beating of strongly coupled electrons and nuclei.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b25d5bcef340e12afbc72c96f7ec3a78 https://doi.org/10.1073/pnas.2205510119 Zobrazit plný text záznamu