Photonics and application of dipyrrinates in the optical devices
| Autor: | Rimma T Kuznetsova, A. A. Prokopenko, D. E. Bashkirtsev, Iu. V. Aksenova, Mikhail B. Berezin, N. A. Dudina |
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| Rok vydání: | 2016 |
| Předmět: |
History
chemistry.chemical_element 02 engineering and technology 010402 general chemistry Photochemistry 01 natural sciences Oxygen Education chemistry.chemical_compound Atom Alkyl chemistry.chemical_classification Singlet oxygen business.industry оптические устройства 021001 nanoscience & nanotechnology 0104 chemical sciences Computer Science Applications chemistry Excited state дипирринаты фотоника Photonics 0210 nano-technology Luminescence business Lasing threshold |
| Zdroj: | Journal of Physics: Conference Series. 2016. Vol. 741. P. 012127 (1-5) |
| ISSN: | 1742-6596 1742-6588 |
| DOI: | 10.1088/1742-6596/741/1/012127 |
| Popis: | In this paper spectral-luminescent, lasing, photochemical, and sensory characteristics of a number of Zn(II) and B(III) coordination complexes with dipyrrinates with different structures are presented. We have discussed relations of the structure of investigated compounds and formed solvates with their optical characteristics. The results showed that alkyl substituted dipyrrinates derivatives have excellent luminescent characteristics and demonstrated effective lasing upon excitation of Nd:YAG-laser. They can be used as active media for liquid tunable lasers. Zinc and boron fluoride complexes of dipyrrinates with heavy atoms in structure don't have fluorescence but have long-lived emission due to increased nonradiative intersystem processes in the excited state by the mechanism of a heavy atom. For solid samples based on halogenated complexes was found dependency of the long-lived emission intensity of the oxygen concentration in gas flow. The presence of line segment indicates the possibility of the use of these complexes as a basis for creation of optical sensors for oxygen. Moreover, results of a study of halogen-substituted aza-complexes under irradiation are presented. Such complexes are promising for the creating media for generation of singlet oxygen (1O2), which is important for photodynamic therapy in medicine and photocatalytic reactions in the industry. |
| Databáze: | OpenAIRE |
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