Transfer Molding of Nanoscale Oxides Using Water-Soluble Templates

Autor: John D. Bass, Charles T. Rettner, Robert D. Miller, Ho-Cheol Kim, Noel Arellano, Charles D. Schaper, Fahhad H. Alharbi
Rok vydání: 2011
Předmět:
Zdroj: ACS Nano. 5:4065-4072
ISSN: 1936-086X
1936-0851
DOI: 10.1021/nn2006514
Popis: We report a facile method for creating nanoscopic oxide structures over large areas that is capable of producing high aspect ratio nanoscale structures with feature sizes below 50 nm. A variety of nanostructured oxides including TiO(2), SnO(2) and organosilicates are formed using sol-gel and nanoparticle precursors by way of molding with water-soluble polymeric templates generated from silicon masters. Sequential stacking techniques are developed that generate unique 3-dimensional nanostructures with combinatorially mixed geometries, scales, and materials. Applicable to a variety of substrates, this scalable method allows access to a broad range of new thin film morphologies for applications in devices, catalysts, and functional surface coatings.
Databáze: OpenAIRE