Expedient Route to the functionalized calyciphylline A-type skeleton via a Michael addition-RCM strategy

Autor:	Benjamin Darses, Iacovos N. Michaelides, Filippo Sladojevich, John W. Ward, Darren J. Dixon
Jazyk:	angličtina
Rok vydání:	2016
Předmět:	Models Molecular Molecular Structure Chemistry Stereochemistry Intramolecular force Organic Chemistry Michael reaction Polycyclic Compounds Anisoles Physical and Theoretical Chemistry Metathesis Key features Biochemistry
Popis:	An efficient, robust, and scalable strategy to access the functionalized core of calyciphylline A-type alkaloids has been developed starting from commercially available 3-methylanisole. Key features of this approach are an intramolecular Michael addition/allylation sequence and a ring-closing metathesis step.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b1e0f82aa1b828fa598629df03520486 https://ora.ox.ac.uk/objects/uuid:89580c4d-b77c-42ba-b72b-7a4dd1195d06 Zobrazit plný text záznamu