Investigation of factors influencing the chemoenzymatic synthesis of block copolymers
| Autor: | Martin Wolffs, CE Cor Koning, Thomas M. Hermans, Ara Anja Palmans, Joris W. Peeters, M Matthijs de Geus, Andreas Heise |
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| Přispěvatelé: | Macro-Organic Chemistry, Chemical Engineering and Chemistry, Macromolecular and Organic Chemistry, Processing and Performance |
| Jazyk: | angličtina |
| Rok vydání: | 2005 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Immobilized enzyme Organic Chemistry technology industry and agriculture Polymer macromolecular substances Ring-opening polymerization Inorganic Chemistry End-group chemistry.chemical_compound chemistry Polymerization Polycaprolactone Polymer chemistry Materials Chemistry Copolymer Bifunctional |
| Zdroj: | Macromolecules, 38(10), 4220-4225. American Chemical Society |
| ISSN: | 0024-9297 |
| DOI: | 10.1021/ma0473871 |
| Popis: | The chemoenzymatic synthesis of block copolymers from a bifunctional initiator using enzymatic ring-opening polymerization (eROP) and ATRP in two consecutive steps was investigated. First, a polycaprolactone (PCL) macroinitiator was obtained via an enzymatic ring-opening polymerization initiated by the bifunctional initiator. By carefully managing the water activity in the system, the amount of PCL not initiated by the bifunctional initiator was reduced to |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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