Gold-Catalyzed cis-Hydroarylation of Ynamides with Indoles: Regio- and Stereoselective Synthesis of a Class of 2-Vinylindoles

Autor:	Elisabetta Rossi, Marco Negrato, Giorgio Abbiati, Valentina Pirovano, Monica Dell'Acqua
Rok vydání:	2016
Předmět:	Class (set theory) Nucleophile 010405 organic chemistry Chemistry Stereochemistry Organic Chemistry Stereoselectivity Physical and Theoretical Chemistry 010402 general chemistry 01 natural sciences Biochemistry 0104 chemical sciences Catalysis
Zdroj:	Organic letters. 18(19)
ISSN:	1523-7052
Popis:	A new gold-catalyzed reaction of ynamides with 3-substituted indoles as nucleophiles is reported. The reaction allows for the synthesis of a new class of 2-vinylindole derivatives in good yields via the intermediacy of a cyclopropyl gold-carbenoid species.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b1d5278f56fd0361747ab76ae2784102 https://pubmed.ncbi.nlm.nih.gov/27612094 Zobrazit plný text záznamu