BODIPY atropisomer interconversion, face discrimination, and superstructure appending
| Autor: | Ewen Bodio, Pierre-Emmanuel Doulain, Richard A. Decréau, Christine Goze, Philippe Richard |
|---|---|
| Přispěvatelé: | Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon] ( ICMUB ), Université de Bourgogne ( UB ) -Centre National de la Recherche Scientifique ( CNRS ), Institut de Chimie Moléculaire de l'Université de Bourgogne [Dijon] (ICMUB), Université de Bourgogne (UB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
spectroscopy
binding Stereochemistry Stacking Append 010402 general chemistry Ring (chemistry) porphyrins 01 natural sciences biomolecules [ CHIM ] Chemical Sciences Catalysis chemistry.chemical_compound dimers Materials Chemistry fluorophores [CHIM]Chemical Sciences Atropisomer 010405 organic chemistry Chemistry Metals and Alloys General Chemistry 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Face discrimination Ceramics and Composites cells fluorescence BODIPY probes Superstructure (condensed matter) moieties |
| Zdroj: | Chemical Communications Chemical Communications, Royal Society of Chemistry, 2016, 52 (24), pp.4474-4477. 〈http://pubs.rsc.org/en/content/articlehtml/2016/cc/c5cc10526a〉. 〈10.1039/c5cc10526a〉 Chemical Communications, Royal Society of Chemistry, 2016, 52 (24), pp.4474-4477. ⟨10.1039/c5cc10526a⟩ |
| ISSN: | 1359-7345 1364-548X |
| DOI: | 10.1039/c5cc10526a〉 |
| Popis: | International audience; A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two inter-convertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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