Recent Development in the Synthesis and Catalytic Application of Iridacycles
| Autor: | Aysecik Kacmaz, Jianliang Xiao, Zhenyu Chen |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
iridacycles
Hydrosilylation General Chemical Engineering 010402 general chemistry Transfer hydrogenation 01 natural sciences Biochemistry Catalysis Carboxylic-Acid Salts chemistry.chemical_compound Direct Reductive Amination Materials Chemistry Chemoselective Transfer Hydrogenation Chelation Dehydrogenation Cp-Asterisk-Ir 010405 organic chemistry Asymmetric hydrogenation hydrosilylation General Chemistry Combinatorial chemistry Versatile Transfer Hydrogenation 0104 chemical sciences Cyclometalated Iridium Complexes cyclometallated complexes chemistry dehydrogenation Methodology Cooperative Catalysis Asymmetric Transfer Hydrogenation transfer hydrogenation N-Heterocyclic-Carbene hydrogenation H-Bond Activation Metallocene |
| Zdroj: | The Chemical Record. |
| ISSN: | 1528-0691 1527-8999 |
| DOI: | 10.1002/tcr.202100051 |
| Popis: | Cyclometallated complexes are well-known and have found many applications. This article provides a short review on the progress made in the synthesis and application to catalysis of cyclometallated half-sandwich Cp*Ir(III) complexes (Cp*: pentamethylcyclopentadienyl) since 2017. Covered in the review are iridacycles featuring conventional C,N chelates and less common metallocene and carbene-derived C,N and C,C ligands. This is followed by an overview of the studies of their applications in catalysis ranging from asymmetric hydrogenation, transfer hydrogenation, hydrosilylation to dehydrogenation. University of Liverpool; Technological Research Council of Turkey (TUBTAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) We thank the University of Liverpool for studentship support (ZYC) and the Technological Research Council of Turkey (TUBTAK) for a postdoctoral fellowship (AK). |
| Databáze: | OpenAIRE |
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