Mixed-conducting ceramic-carbonate membranes exhibiting high CO2/O2 permeation flux and stability at high temperatures
Autor: | Beatriz Zeifert, R. Ortega-Lugo, Oscar Ovalle-Encinia, José Ortiz-Landeros, Carlos Gómez-Yáñez, J.A. Fabián-Anguiano |
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Jazyk: | angličtina |
Rok vydání: | 2020 |
Předmět: |
CO2 separation
Materials science 02 engineering and technology Permeance 010402 general chemistry 01 natural sciences lcsh:TP785-869 O2 separation Ceramic Perovskite (structure) ceramic–carbonate membrane selectivity Atmospheric temperature range Permeation 021001 nanoscience & nanotechnology Microstructure 0104 chemical sciences Electronic Optical and Magnetic Materials Membrane Chemical engineering lcsh:Clay industries. Ceramics. Glass visual_art Ceramics and Composites visual_art.visual_art_medium Chemical stability 0210 nano-technology |
Zdroj: | Journal of Advanced Ceramics, Vol 9, Iss 1, Pp 94-106 (2020) |
ISSN: | 2227-8508 2226-4108 |
Popis: | This investigation demonstrates the feasibility to fabricate high quality ceramic-carbonate membranes based on mixed-conducting ceramics. Specifically, it is reported the simultaneous CO2/O2 permeation and stability properties of membranes constituted by a combination of ceramic and carbonate phases, wherein the microstructure of the ceramic part is composed, in turn, of a mixture of fluorite and perovskite phases. These ceramics showed ionic and electronic conduction, and at the operation temperature, the carbonate phase of the membranes is in liquid state, which allows the transport of $$\rm{CO}_3^{2-}$$CO32− and O2− species via different mechanisms. To fabricate the membranes, the ceramic powders were uniaxially pressed in a disk shape. Then, an incipient sintering treatment was carried out in such a way that a highly porous ceramic was obtained. Afterwards, the piece is densified by the infiltration of molten carbonate. Characterization of the membranes was accomplished by SEM, XRD, and gas permeation techniques among others. Thermal and chemical stability under an atmosphere rich in CO2 was evaluated. CO2/O2 permeation and long-term stability measurements were conducted between 850 and 940 °C.The best permeation-separation performance of membranes of about 1 mm thickness, showed a maximum permeance flux of about 4.46×10−7 mol·m−2·s−2·Pa−1 for CO2 and 2.18×10−7 mol·m−2·s−1·Pa−1 for O2 at 940 °C. Membranes exhibited separation factor values of 150–991 and 49–511 for CO2/N2 and O2/N2 respectively in the studied temperature range. Despite long-term stability test showed certain microstructural changes in the membranes, no significant detriment on the permeation properties was observed along 100 h of continuous operation. |
Databáze: | OpenAIRE |
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