The importance of crystal size for breathing kinetics in MIL-53(Al)

Autor:	Volodymyr Bon, Nikita Busov, Irena Senkovska, Nadine Bönisch, Leila Abylgazina, Azat Khadiev, Dmitri Novikov, Stefan Kaskel
Jazyk:	angličtina
Rok vydání:	2022
Předmět:	ddc:540 Materials Chemistry Metals and Alloys Ceramics and Composites General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials
Zdroj:	Chemical communications 58(75), 10492-10495 (2022). doi:10.1039/D2CC02662G
DOI:	10.3204/pubdb-2022-04630
Popis:	Chemical communications 58(75), 10492 - 10495 (2022). doi:10.1039/D2CC02662G Herein we analyze the switching kinetics of a breathing framework MIL-53(Al) with respect to different crystallite size regimes. Synchrotron time-resolved powder X-ray diffraction (PXRD) and adsorption rate analysis of n-butane physisorption at 298 K demonstrate the decisive role of crystal size affecting the time domain of breathing transitions in MIL-53(Al). Published by Soc., Cambridge
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b12ee887922fe2c7929ec7e5ca0a823b