Intramolecular palladium-catalyzed allylic alkylation: enantio- and diastereoselective synthesis of [2.2.2] bicycles

Autor:	Naoyuki Asakawa, Gretchen M. Schroeder, Karna L. Sacchi, Barry M. Trost
Rok vydání:	2002
Předmět:	Bicyclic molecule Alkylation Quinine Organic Chemistry chemistry.chemical_element Stereoisomerism Biochemistry Catalysis Tsuji–Trost reaction Alkaloids chemistry Heterocyclic Compounds Intramolecular force Organic chemistry Physical and Theoretical Chemistry Palladium
Zdroj:	Organic letters. 4(20)
ISSN:	1523-7060
Popis:	Pd-catalyzed asymmetric allylic alkylation provides both enantio- and diastereoselectivity in formation of bicyclo [2.2.2] octan-2,3-diones and quinuclidin-2-ones, the latter potential precursors to quinine alkaloids. [reaction: see text]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b0e3c87457e737783c1a7ad95958147e https://pubmed.ncbi.nlm.nih.gov/12323035 Zobrazit plný text záznamu