On the cleavage process of the N-trifluoromethylsulfonyloxy-1,8-naphthalimide photoacid generator

Autor:	Shota Suzuki, Xavier Allonas, Fabrice Morlet-Savary, Shigeru Takahara, Tsuguo Yamaoka, Jean Pierre Fouassier, Jean-Pierre Malval
Přispěvatelé:	Turck, Colette
Rok vydání:	2007
Předmět:	chemistry.chemical_classification [CHIM.MATE] Chemical Sciences/Material chemistry Infrared General Physics and Astronomy Photoacid generator Cleavage (crystal) Sulfonic acid Photochemistry Fluorescence Homolysis chemistry Picosecond Physical and Theoretical Chemistry Bond cleavage
Zdroj:	Chemical Physics Letters. 443:323-327
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2007.06.082
Popis:	The photocleavage mechanism of N -trifluoromethylsulfonyloxy-1,8-naphthalimide usable as a photoacid generator is reported. Stationary fluorescence measurements, picosecond transient spectroscopy, infrared analysis and DFT calculations support a homolytic N–O bond cleavage followed by an internal cyclic rearrangement of the 1,8 naphthalimide core which lead to benz[cd]indol-2(1H)-one, carbon dioxide and sulfonic acid.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b0d7f2aa32b01b8531c031b53d7601a4 https://doi.org/10.1016/j.cplett.2007.06.082 Zobrazit plný text záznamu Full Text from ScienceDirect