Platinum diimine-dithiolate complexes as a new class of photoconducting compounds for pristine photodetectors: case study on [Pt(bipy)(Naph-edt)] (bipy = 2,2'-bipyridine; Naph-edt2- = 2-naphthylethylene-1,2-dithiolate)

Autor: Anna Pintus, Dario Natali, Claudia Caltagirone, Vito Lippolis, Massimiliano Arca, Marco Sampietro, M. Carla Aragoni, Maddalena Binda, Enrico Podda
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Popis: The photoconducting properties of platinum diimine-dithiolate complex [Pt(bipy)(Naph-edt)] (1; bipy = 2,2′-bipyridine; Naph-edt2− = 2-naphthylethylene-1,2-dithiolate) were investigated. DFT calculations on a model assembly with four complex units suggest that the high external quantum efficency measured on a prototype photodetector correlates with the intermolecular character of electronic excitations in the visible region.
Databáze: OpenAIRE