Hydrogen recovery from the purge stream of a cyclohexane production process using a mass exchange heuristic

Autor: Carlos Daniel Fischer, Oscar Alberto Iribarren
Rok vydání: 2014
Předmět:
Zdroj: International Journal of Hydrogen Energy. 39:20094-20104
ISSN: 0360-3199
DOI: 10.1016/j.ijhydene.2014.10.042
Popis: In this paper, we propose a novel hydrogen recovery structure in a cyclohexane production process, arrived at by following a mass exchange heuristic developed in previous works [1,2]. In the cyclohexane production process considered, we explore the effect of process design variables and find the optimal design for a mass exchange between the purge stream and the feed of benzene to the process. We compare our results with a conventional process design lacking hydrogen recovery from the purge, and with a process design which implements a conventional membrane recovery system at the optimum setup of the decision variables. The process with recovery through mass exchange here proposed obtained a respectable 7.12% reduction of hydrogen consumption, resulting in an increase of the plant Net Annual Income of a 4.24% respect to the conventional process design without recovery. These figures are similar to the ones that result from implementing a process design with a conventional membrane recovery system. These results highlight the importance of considering a mass exchange between the process feed and purge stream as an alternative design of the recovery system. Fil: Fischer, Carlos Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; Argentina Fil: Iribarren, Oscar Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Desarrollo y Diseño (i); Argentina. Universidad Tecnológica Nacional. Facultad Regional Reconquista; Argentina
Databáze: OpenAIRE