Single-molecule conductance investigation of BDT derivatives: an additional pattern found to induce through-space channels beyond π-π stacking
| Autor: | Rongsheng Chen, Yunchuan Li, Shuai Chang, Bohuai Xiao, Jianqiao Dong, Yichong Liu, Haijian Chen |
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| Rok vydání: | 2019 |
| Předmět: |
Materials science
010405 organic chemistry Metals and Alloys Stacking Conductance General Chemistry 010402 general chemistry Space (mathematics) 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Chemical physics Materials Chemistry Ceramics and Composites Molecule Communication channel |
| Zdroj: | Chemical communications (Cambridge, England). 55(57) |
| ISSN: | 1364-548X |
| Popis: | The through-space conductance of individual molecules is supposed to improve the macroscopic carrier movement, but the most widely acclaimed through-space conductance channel just existed in sufficiently close π–π stacked benzene rings. As a breakthrough to this primary cognition, additional conducting channels were confirmed to exist in non-strict face-to-face aligned thiophenes or phenyl-thiophene in BDT derivatives for the first time. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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