1,1'-Diphenyl-bis(silatrane) as the First Structurally Characterized bis(silatrane)

Autor: Yu. Wang, D. M. Vakhrusheva, I. V. Krylova, A. Ya. Kozmenkova, E. N. Nikolaevskaya, B. N. Mankaev, M. E. Minyaev, M. A. Syroeshkin, M. P. Egorov, V. V. Jouikov
Přispěvatelé: Institut des Sciences Chimiques de Rennes (ISCR), Université de Rennes (UR)-Institut National des Sciences Appliquées - Rennes (INSA Rennes), Institut National des Sciences Appliquées (INSA)-Institut National des Sciences Appliquées (INSA)-Ecole Nationale Supérieure de Chimie de Rennes (ENSCR)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), ND Zelinsky Institute of Organic Chemistry [Moscow, Russia], Mendeleev University of Chemical Technology of Russia, Russian Science FoundationRussian Science Foundation (RSF) [18-73-10180]
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry
Koordinatsionnaya Khimiya / Russian Journal of Coordination Chemistry, 2022, 48 (2), pp.69-74. ⟨10.1134/S1070328422010079⟩
ISSN: 1070-3284
1608-3318
Popis: International audience; 1,1'-Diphenyl-bis(silatrane) (I) was obtained by the reaction of tris(1,3-dihydroxypropan-2-yl)amine (L) with PhSi(OEt)(3) in toluene. The molecular structure of complex I was established by X-ray diffraction (CIF file CCDC no. 2078347). Study of the redox properties of new bis(silatrane) I demonstrated that its radical ions generated by cyclic voltammetry are stable since the radical center located on the nitrogen atom is sterically protected within the bis(atrane) cage.
Databáze: OpenAIRE
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