Graphene Oxide/Co3O4 Nanocomposite: Synthesis, Characterization, and Its Adsorption Capacity for Removal of Organic Dye Pollutants from Water
| Autor: | Yaghoub Mansourpanah, Kolsoum Pourzare, Saeed Farhadi |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: |
Materials science
Oxide Organic dyes 02 engineering and technology 010402 general chemistry 01 natural sciences law.invention lcsh:Chemistry chemistry.chemical_compound symbols.namesake Hydrothermal decomposition Nanocomposite Adsorption Physisorption law Co3O4 nanoparticles Graphene oxide nanosheets Rhodamine B Methyl orange Adsorption performance Nanocomposite Graphene Langmuir adsorption model 021001 nanoscience & nanotechnology 0104 chemical sciences Chemical engineering chemistry lcsh:QD1-999 symbols 0210 nano-technology |
| Zdroj: | Acta Chimica Slovenica, Vol 64, Iss 4, Pp 945-958 (2017) |
| ISSN: | 1580-3155 1318-0207 |
| Popis: | In this work, graphene oxide/Co 3 O 4 nanocomposite was synthesized via hydrothermal decomposition of [Co(en) 3 ](NO 3 ) 3 complex onto graphene oxide nanosheets. The as-prepared nanocomposite (denoted as GO/Co 3 O 4 ) was structurally characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopies (TEM and SEM), energy dispersive X-ray (EDX) spectroscopy, magnetic measurements, and N 2 adsorption–desorption analysis. The results demonstrated successful immobilization of Co 3 O 4 nanoparticles with an average diameter size of around 12.5 nm on the surface of graphene oxide nanosheets. The adsorption performance of GO/Co 3 O 4 nanocomposite was investigated towards different organic dyes in aqueous solutions. The results displayed that the adsorption rate of the GO/Co 3 O 4 nanocomposite was 98% for methylene blue (MB) in 12 min, and 66% and 45% for Rhodamine B (RhB) and methyl orange (MO) in 40 min, respectively. The effects of various important parameters including adsorbent dosage, contact time, pH, and temperature on the adsorption process were investigated in detail. The equilibrium adsorption data were better fitted by Langmuir isotherm. Adsorption kinetics is well-modeled using pseudo-second-order model. Different thermodynamic parameters indicated that the adsorption process was physisorption and spontaneous. The findings of the present work highlighted facile fabrication of GO/Co 3 O 4 and its application for rapid and efficient removal of MB from wastewater. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|