Pd(0)-Catalyzed Cross-Coupling of 1,1-Diboronates with 2,2′-Dibromobiphenyls: Synthesis of 9H-Fluorenes

Autor:	Jianbo Wang, Yan Zhang, Xianghang Shangguan, Shuai Xu, Huan Li
Rok vydání:	2015
Předmět:	Coupling Reaction conditions Fluorenes Molecular Structure Stereochemistry Chemistry media_common.quotation_subject Biphenyl Compounds Organic Chemistry Boronic Acids Catalysis Computational chemistry Simplicity Palladium media_common
Zdroj:	The Journal of Organic Chemistry. 80:7779-7784
ISSN:	1520-6904 0022-3263
DOI:	10.1021/acs.joc.5b01100
Popis:	An efficient and mild synthesis of 9H-fluorene derivatives through a Pd(0)-catalyzed cross-coupling reaction of 1,1-diboronates with 2,2'-dibromobiphenyls has been developed. This reaction features high yields, operational simplicity, and mild reaction conditions, thus providing an excellent alternative to published methods for 9H-fluorene synthesis.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afdd4cb933acb62d88677d17cf41c87f https://doi.org/10.1021/acs.joc.5b01100 Zobrazit plný text záznamu