Synthesis and characterisation of vanadium(III) complexes of biphenylphenols

Autor:	SHARMA, Neeraj, CHAUDHRY, Maridula Thakur And Subhash Chand, THAKUR, Maridula
Rok vydání:	2010
Předmět:	General Chemistry Vanadium(III) complexes biphenylphenols magnetic study electronic spectra mass spectra
Zdroj:	Volume: 34, Issue: 4 593-602 Turkish Journal of Chemistry
ISSN:	1303-6130 1300-0527
DOI:	10.3906/kim-0907-124
Popis:	The vanadium(III) complexes of composition [VCl3-n(OAr1,2)n.(THF)2] (OAr1 = 2-phenylphenoxo and OAr2 = 4-phenylphenoxo, THF = tetrahydrofuran; n = 1 /to 3) were prepared by in situ reaction of VCl3.(THF)3 with sodium salt of respective phenols in tetrahydrofuran. The complexes were characterised by elemental analysis, molar conductance, FTIR, UV-Vis, and FAB-mass spectral and magnetic studies. The thermal behaviour of some of the complexes was studied by TG-DTA. The dinuclear phenoxy bridged octahedral structures for the complexes were inferred from the spectral and magnetic studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afd2a86e9c4e6cf267613297f6a5d215 https://doi.org/10.3906/kim-0907-124 Zobrazit plný text záznamu