Two Divergent Enyne Cycloisomerization Routes Mediated by Monoallenylidene Pd(II) Catalysts

Autor:	Yuan Zhang, Yu-Jiang Wang, Qiang Zou, Xiao-Yu Liu, Zili Chen
Rok vydání:	2022
Předmět:	Organic Chemistry Physical and Theoretical Chemistry Biochemistry
Zdroj:	Organic letters. 24(44)
ISSN:	1523-7052
Popis:	The catalytic application of four monoallenylidene bisphosphine Pd(II) catalysts, which were developed using alkynyl triazole salt as the allenylidene source, in the cycloisomerization of 1,6-enyne was explored. Two divergent reaction pathways, including a new type of intramolecular Alder-ene (IMAE) route and a routine cycloisomerization route, were developed using either complex TAA(Et
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::afc860039df4f52c8b3316b5a011a26a https://pubmed.ncbi.nlm.nih.gov/36300900 Zobrazit plný text záznamu