Phenyloxenium Ions: More Like Phenylnitrenium Ions than Isoelectronic Phenylnitrenes?
| Autor: | Patrick J. Hanway, Arthur H. Winter |
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| Rok vydání: | 2011 |
| Předmět: | |
| Zdroj: | Journal of the American Chemical Society. 133:5086-5093 |
| ISSN: | 1520-5126 0002-7863 |
| Popis: | The geometries and energies of the electronic states of phenyloxenium ion 1 (Ph-O(+)) were computed at the multireference CASPT2/pVTZ level of theory. Despite being isoelectronic to phenylnitrene 4, the phenyloxenium ion 1 has remarkably different energetic orderings of its electronic states. The closed-shell singlet configuration ((1)A(1)) is the ground state of the phenyloxenium ion 1, with a computed adiabatic energy gap of 22.1 kcal/mol to the lowest-energy triplet state ((3)A(2)). Open-shell singlet configurations ((1)A(2), (1)B(1), (1)B(2), 2(1)A(1)) are significantly higher in energy (30 kcal/mol) than the closed-shell singlet configuration. These values suggest a revision to the current assignments of the ultraviolet photoelectron spectroscopy bands for the phenoxy radical to generate the phenyloxenium ion 1. For para-substituted phenyloxenium ions, the adiabatic singlet-triplet energy gap (ΔE(ST)) is found to have a positive linear free energy relationship with the Hammett-like σ(+)(R)/σ(+) substituent parameters; for meta substituents, the relationship is nonlinear and negatively correlated. CASPT2 analyses of the excited states of p-aminophenyloxenium ion 5 and p-cyanophenyloxenium ion 10 indicate that the relative orderings of the electronic states remain largely unperturbed for these para substitutions. In contrast, meta-donor-substituted phenyloxenium ions have low-energy open-shell states (open-shell singlet, triplet) due to stabilization of a π,π* diradical state by the donor substituent. However, all of the other phenyloxenium ions and larger aryloxenium ions (naphthyl, anthryl) included in this study have closed-shell singlet ground states. Consequently, ground-state reactions of phenyloxenium ions are anticipated to be more closely related to closed-shell singlet arylnitrenium ions (Ar-NH(+)) than their isoelectronic arylnitrene (Ar-N) counterparts. |
| Databáze: | OpenAIRE |
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