Some aspects of radical chemistry in the assembly of complex molecular architectures
| Autor: | Samir Z. Zard, Beatrice Quiclet‐Sire |
|---|---|
| Přispěvatelé: | Laboratoire de synthèse organique (DCSO), École polytechnique (X)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS) |
| Rok vydání: | 2013 |
| Předmět: |
radical vinylation
[CHIM.ORGA]Chemical Sciences/Organic chemistry 010405 organic chemistry Chemistry Radical radical allylation education Organic Chemistry Intermolecular force Nanotechnology Review Bond formation 010402 general chemistry 01 natural sciences xanthate transfer 0104 chemical sciences lcsh:QD241-441 Electron transfer iminyls lcsh:Organic chemistry amidyls lcsh:Q lcsh:Science |
| Zdroj: | Beilstein Journal of Organic Chemistry Beilstein Journal of Organic Chemistry, Beilstein-Institut, 2013, 9, pp.557-576. ⟨10.3762/bjoc.9.61⟩ Beilstein Journal of Organic Chemistry, Vol 9, Iss 1, Pp 557-576 (2013) |
| ISSN: | 1860-5397 |
| DOI: | 10.3762/bjoc.9.61 |
| Popis: | International audience; This review article describes briefly some of the radical processes developed in the authors' laboratory as they pertain to the concise assembly of complex molecular scaffolds. The emphasis is placed on the use of nitrogen-centred radicals, on the degenerate addition-transfer of xanthates, especially on its potential for intermolecular carbon-carbon bond formation, and on the generation and capture of radicals through electron transfer processes. |
| Databáze: | OpenAIRE |
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